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17, can be built using a double-compartment LB trough, by dipping the substrate into the compartment containing monolayer A, and withdrawing from the compartment containing monolayer B. More detailed discussion of different constructions of an LB trough will be given later. 16 Langmuir-Blodgett deposition process: (a) dipping a hydrophobic substrate, and (b) withdrawing the substrate. where AL is the reduction in the total area occupied by the monolayer, and AS is the area of the substrate coated with the film.

Proteins, immune-components, DNA, cells, and viruses), and inorganic and polymer particles, can be incorporated into the polymer film matrix by simple alternation with layers of polyions of opposite charge. In order to be suitable for ESA deposition, these objects must have the electric charge distributed over the whole surface. In this case, part of the electric charge will be engaged in binding the polyion underlayer, while the remaining charge will be available for binding the next polyion layer.

Proteins are also electrically charged depending on their isoelectric point and the pH of the buffer solution. As regards to organic macromolecules, they must contain several ionic groups in a three-dimensional arrangement. The following examples of composite ESA films demonstrate the high versatility of this deposition technique. , organic dyes) containing ionic groups can be deposited by ESA + − technique. The most common ionic substituting groups are SO3 Na and + NH3 , although many others can be used.

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A 10-point circle is associated with any general point of the ellipse. New properties of Fagnanos point by Ternullo M.


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